pfsync: Avoid transmitting uninitialized bytes in pfsync_sendout()

When IPv6 support was added to pfsync, PFSYNC_MINPKT increased such that
we always allocate enough space for either IPv4 or IPv6 headers. IPv6
headers are 20 bytes larger than IPv4 headers. When pfsync_sendout()
does its thing, it ends up allocating enough space for either; thus when
transmitting an IPv4 packet, the last 20 bytes of the buffer are left
uninitialized.

Fix the problem by stashing the length in a local variable and adjusting
it depending on the address family in use.

While here, just zero the entire buffer in one go rather than being
careful to initialize each subheader. This seems simpler and less error
prone.

Reported by: KMSAN
Reviewed by: kp
Fixes: 6fc7fc2dbb2b ("pfsync: transport over IPv6")
MFC after: 3 days
Differential Revision: https://reviews.freebsd.org/D42461